BENZENE (AMOCO/TOTAL)

From: Subject: BENZENE (AMOCO/TOTAL) Date: Fri, 15 Nov 2002 01:24:37 -0500 MIME-Version: 1.0 Content-Type: multipart/related; boundary="----=_NextPart_000_011E_01C28C45.C324DC00"; type="text/html" X-MimeOLE: Produced By Microsoft MimeOLE V5.50.4133.2400 This is a multi-part message in MIME format. ------=_NextPart_000_011E_01C28C45.C324DC00 Content-Type: text/html; charset="iso-8859-1" Content-Transfer-Encoding: quoted-printable Content-Location: http://siri.org/msds/mf/amoco/files/11697000.html BENZENE (AMOCO/TOTAL)

MATERIAL SAFETY DATA SHEET

BENZENE = (AMOCO/TOTAL)

MSDS No.=20 11697000 ANSI/ENGLISH=20

1.0 CHEMICAL PRODUCT AND = COMPANY=20 IDENTIFICATION

PRODUCT NAME: BENZENE (AMOCO/TOTAL)=20

MANUFACTURER/SUPPLIER:

Amoco Oil = Company
200=20 East Randolph Drive
Chicago, Illinois 60601 U.S.A.

EMERGENCY HEALTH INFORMATION:
1 (800) 447-8735=20
EMERGENCY SPILL INFORMATION:
1 (800) 424-9300 = CHEMTREC=20 (USA)=20
OTHER PRODUCT SAFETY INFORMATION:
(312) = 856-3907=20

2.0 COMPOSITION/INFORMATION ON = INGREDIENTS

Component=20	CAS#=20	Range % by Wt.
Benzene=20	71-43-2=20	99.80=20
Toluene=20	108-88-3=20	0.20

(See Section 8.0, "Exposure Controls/Personal Protection", for = exposure=20 guidelines)=20

3.0 HAZARDS IDENTIFICATION

EMERGENCY OVERVIEW: Danger! Extremely flammable. Causes = eye and=20 skin irritation. Inhalation causes headaches, dizziness, drowsiness, and = nausea,=20 and may lead to unconsciousness. Harmful or fatal if liquid is aspirated = into=20 lungs. Danger! Contains Benzene. Cancer hazard. Can cause blood = disorders.=20 Harmful when absorbed through the skin.=20

POTENTIAL HEALTH EFFECTS: =20

EYE CONTACT: Causes mild eye irritation.=20

SKIN CONTACT: Causes mild skin irritation. Causes skin = irritation=20 on prolonged or repeated contact. Harmful when absorbed through the = skin.=20

INHALATION: Cancer hazard. Can cause blood disorders. = Inhalation=20 causes headaches, dizziness, drowsiness, and nausea, and may lead to=20 unconsciousness. See "Toxicological Information" section (Section 11.0). =

INGESTION: Harmful or fatal if liquid is aspirated into = lungs.=20 See "Toxicological Information" section (Section 11.0).=20

HMIS CODE: (Health:2) (Flammability:3) (Reactivity:0)=20

NFPA CODE: (Health:2) (Flammability:3) (Reactivity:0)=20

4.0 FIRST AID MEASURES

EYE: Flush eyes with plenty of water for at least 15 = minutes. Get=20 medical attention if irritation persists.=20

SKIN: Wash exposed skin with soap and water. Remove = contaminated=20 clothing, including shoes, and thoroughly clean and dry before reuse. = Get=20 medical attention if irritation develops.=20

INHALATION: If adverse effects occur, remove to = uncontaminated=20 area. Give artificial respiration if not breathing. Get immediate = medical=20 attention.=20

INGESTION: If swallowed, drink plenty of water, do NOT = induce=20 vomiting. Get immediate medical attention.=20

5.0 FIRE FIGHTING MEASURES

FLASHPOINT: 12=B0F(-11=B0C)=20

UEL: 8.0%=20

LEL: 1.5%=20

AUTOIGNITION TEMPERATURE: 928=B0F (498=B0C)=20

FLAMMABILITY CLASSIFICATION: Extremely Flammable Liquid.=20

EXTINGUISHING MEDIA: Agents approved for Class B hazards = (e.g.,=20 dry chemical, carbon dioxide, foam, steam) or water fog.=20

UNUSUAL FIRE AND EXPLOSION HAZARDS: Extremely flammable = liquid.=20 Vapor may explode if ignited in enclosed area.=20

FIRE-FIGHTING EQUIPMENT: Firefighters should wear full = bunker=20 gear, including a positive pressure self-contained breathing apparatus.=20

PRECAUTIONS: Keep away from sources of ignition (e.g., = heat and=20 open flames). Keep container closed. Use with adequate ventilation.=20

HAZARDOUS COMBUSTION PRODUCTS: Incomplete burning can = produce=20 carbon monoxide and/or carbon dioxide and other harmful products.=20

6.0 ACCIDENTAL RELEASE = MEASURES

Remove or shut=20 off all sources of ignition. Remove mechanically or contain on an = absorbent=20 material such as dry sand or earth. Increase ventilation if possible. = Wear=20 respirator and spray with water to disperse vapors. Keep out of sewers = and=20 waterways.=20

7.0 HANDLING AND STORAGE

HANDLING: Use with adequate ventilation. Do not breathe = vapors.=20 Keep away from ignition sources (e.g., heat, sparks, or open flames). = Ground and=20 bond containers when transferring materials. Wash thoroughly after = handling.=20 After this container has been emptied, it may contain flammable vapors; = observe=20 all warnings and precautions listed for this product.=20

STORAGE: Store in flammable liquids storage area. Store = away from=20 heat, ignition sources, and open flame in accordance with applicable=20 regulations. Keep container closed. Outside storage is recommended.=20

8.0 EXPOSURE CONTROLS / PERSONAL = PROTECTION

EYE: Do not get in eyes. Wear eye protection.=20

SKIN: Do not get on skin or clothing. Wear protective = clothing=20 and gloves.=20

INHALATION: Do not breathe mist or vapor. If heated and=20 ventilation is inadequate, use supplied-air respirator approved by = NIOSH/MSHA.=20

ENGINEERING CONTROLS: Control airborne concentrations = below the=20 exposure guidelines.

EXPOSURE GUIDELINES:

Component=20	CAS#=20	Exposure Limits
Benzene=20	71-43-2=20	OSHA PEL: 1 ppm OSHA STEL: 5 ppm ACGIH = TLV-TWA:=20 10 ppm=20
Toluene=20	108-88-3=20	OSHA PEL: 100 ppm (1989); 200 ppm (1971) OSHA = STEL:=20 150 ppm (1989); Not established. (1971) OSHA Ceiling: 300 ppm = (1971)=20 ACGIH TLV-TWA: 50 ppm (skin)

9.0 CHEMICAL AND PHYSICAL PROPERTIES

APPEARANCE AND ODOR: Liquid. Colorless. Sweet odor.=20

pH: Not determined.=20

VAPOR PRESSURE: 74.6 mm Hg at 20 =B0C=20

VAPOR DENSITY: Not determined.=20

BOILING POINT: 176=B0F(80=B0C)=20

MELTING POINT: 42=B0F(6=B0C)=20

SOLUBILITY IN WATER: Slight, 0.1 to 1.0%.=20

SPECIFIC GRAVITY (WATER=3D1): 0.88=20

10.0 STABILITY AND REACTIVITY

STABILITY: Stable.=20

CONDITIONS TO AVOID: Keep away from ignition sources = (e.g. heat,=20 sparks, and open flames).=20

MATERIALS TO AVOID: Avoid chlorine, fluorine, and other = strong=20 oxidizers.=20

HAZARDOUS DECOMPOSITION: None identified.=20

HAZARDOUS POLYMERIZATION: Will not occur.=20

11.0 TOXICOLOGICAL = INFORMATION

ACUTE=20 TOXICITY DATA: =20

EYE IRRITATION: Testing not conducted. See Other = Toxicity Data.=20

SKIN IRRITATION: Testing not conducted. See Other = Toxicity=20 Data.=20

DERMAL LD50: Testing not conducted. See Other Toxicity = Data.=20

ORAL LD50: 3.8 g/kg (rat).=20

INHALATION LC50: 10000 ppm (rat)

OTHER TOXICITY DATA: Acute toxicity of benzene results = primarily=20 from depression of the central nervous system (CNS). Inhalation of=20 concentrations over 50 ppm can produce headache, lassitude, weariness,=20 dizziness, drowsiness, or excitation. Exposure to very high levels can = result in=20 unconsciousness and death.=20

Long-term overexposure to benzene has been associated with certain = types of=20 leukemia in humans. In addition, the International Agency for Research = on Cancer=20 (IARC) and OSHA consider benzene to be a human carcinogen. Chronic = exposures to=20 benzene at levels of 100 ppm and below have been reported to cause = adverse blood=20 effects including anemia. Benzene exposure can occur by inhalation and=20 absorption through the skin.=20

Inhalation and forced feeding studies of benzene in laboratory = animals have=20 produced a carcinogenic response in a variety of organs, including = possibly=20 leukemia, other adverse effects on the blood, chromosomal changes and = some=20 effects on the immune system. Exposure to benzene at levels up to 300 = ppm did=20 not produce birth defects in animal studies; however, exposure to the = higher=20 dosage levels (greater than 100 ppm) resulted in a reduction of body = weight of=20 the rat pups (fetotoxicity). Changes in the testes have been observed in = mice=20 exposed to benzene at 300 ppm, but reproductive performance was not = altered in=20 rats exposed to benzene at the same level.=20

Aspiration of this product into the lungs can cause chemical = pneumonia and=20 can be fatal. Aspiration into the lungs can occur while vomiting after = ingestion=20 of this product. Do not siphon by mouth.=20

12.0 ECOLOGICAL = INFORMATION

Ecological testing=20 has not been conducted on this product.=20

13.0 DISPOSAL INFORMATION

Disposal = must be in=20 accordance with applicable federal, state, or local regulations.=20 Enclosed-controlled incineration is recommended unless directed = otherwise by=20 applicable ordinances. Residues and spilled material are hazardous waste = due to=20 ignitability.=20

14.0 TRANSPORTATION INFORMATION

U.S. DEPT OF TRANSPORTATION

Shipping Name	Benzene=20
Hazard Class=20	3=20
Identification Number=20	UN1114=20
Packing Group=20	II=20
RQ=20	RQ

INTERNATIONAL INFORMATION:

Sea (IMO/IMDG)

Shipping Name

Not determined.

Air (ICAO/IATA)

Shipping Name

Not determined.

European Road/Rail (ADR/RID)

Shipping Name

Not determined.

Canadian Transportation of Dangerous Goods

Shipping Name

Not determined.

15.0 REGULATORY INFORMATION

CERCLA SECTIONS 102a/103 HAZARDOUS SUBSTANCES (40 CFR Part = 302.4):=20 This product is reportable under 40 CFR Part 302.4 because it contains = the=20 following substance(s):=20

Component/CAS Number=20	Weight %=20	Component Reportable Quantity (RQ)
Benzene 71-43-2=20	99.80=20	10 lbs.

SARA TITLE III SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES (40 = CFR Part=20 355): This product is not regulated under Section 302 of SARA and 40 CFR = Part=20 355.

SARA TITLE III SECTIONS 311/312 HAZARDOUS CATEGORIZATION (40 CFR = Part=20 370): This product is defined as hazardous by OSHA under 29 CFR = Part=20 1910.1200(d).

SARA TITLE III SECTION 313 (40 CFR Part 372): This product = contains=20 the following substance(s), which is on the Toxic Chemicals List in 40 = CFR Part=20 372:=20

Component/CAS Number=20	Weight Percent
Benzene 71-43-2=20	99.80

U.S. INVENTORY (TSCA): Listed on inventory.=20

OSHA HAZARD COMMUNICATION STANDARD: Flammable liquid. = Carcinogen.=20 Irritant. CNS Effects. Target organ effects.=20

EC INVENTORY (EINECS/ELINCS): In compliance.=20

JAPAN INVENTORY (MITI): Not determined.=20

AUSTRALIA INVENTORY (AICS): Not determined.=20

KOREA INVENTORY (ECL): Not determined.=20

CANADA INVENTORY (DSL): Not determined.=20

PHILIPPINE INVENTORY (PICCS): Not determined.=20

16.0 OTHER INFORMATION

Prepared by:

Environment, Health and Safety = Department=20

Issued: November 14, 1995=20

This material Safety Data Sheet conforms to the requirements of ANSI = Z400.1.=20
This material safety data sheet and the information it contains is = offered to=20 you in good faith as accurate. We have reviewed any information = contained in=20 this data sheet which we received from sources outside our company. We = believe=20 that information to be correct but cannot guarantee its accuracy or=20 completeness. Health and safety precautions in this data sheet may not = be=20 adequate for all individuals and/or situations. It is the user's = obligation to=20 evaluate and use this product safely and to comply with all applicable = laws and=20 regulations. No statement made in this data sheet shall be construed as = a=20 permission or recommendation for the use of any product in a manner that = might=20 infringe existing patents. No warranty is made, either express or = implied.=20
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